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The equations for the individual P , Q and R subband branches are the same as those for linear molecules In order to distinguish between different subband branches, one uses the superscript P and R for the corresponding A K selection rule, eg, pQ~ll(J") for a Q-branch transition with AK = 1 The Q-branches may stand out against the other wide spread branch lines This is true of our example of the CH3I spectrum, which exhibits several perpendicular bands (see Fig 43-8) This spectrum also shows the line intensity alteration in the Q branches as a result of spin statistics So far we have neglected rotation-vibration interaction The rotational energy levels in a degenerate vibrational state of a symmetric top with a threefold or higher symmetry axis receive a contribution from Coriolis coupling.

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To get more detailed histories of Linux, I recommend visiting the LWN.net site. LWN.net has kept a detailed Linux timeline from 1998 to the present day. For example, the 2006 timeline is available at http://lwn.net/Articles/Timeline2006. Another good resource is the book Open Sources: Voices from the Open Source Revolution (O Reilly). The whole first edition (published in 1999) is available online (www.oreilly.com/catalog/opensources/book/toc.html).

If SQL Server Management Studio (the client application) executes a batch that calls stored procedure A, which then calls stored procedure B, there are multiple ways procedure B can pass data back to procedure A or to the client application, as illustrated in Figure 24-2.

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This is expressed by the addition,ii1 term of L ~ ~ < , , , I A [ , with C, the Coriolis coupling constant, terminating the degeneracy of ,K, the levels The transitions in a perpendicular band involving ground state and degenerate vibrational state are thus affected by the shift of the individual subband origins, so that a new effective upper state rotational constant Aiz,,(I 2<r ,l)can be obtained from the subband centers, leaving the rotational subband structure unaffected The notably different Q branch spacings in the three most intensive perpendicular bands of CHlI can be explained by this extended model IJI Fig 43-9 a high resolution spectrum of NH3 (oblate symmetric top) is displayed The most intense infrared vibration, which is the y fundamental, shows the features of a parallel band, although with the notable structure of a Q branch doublet at 93 1.

Creating the account management library Using the account management library Working with library methods

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7 cm and 9683 c m ~ This doublet arises from inversion doubling, which is due to the two possible opposite pyramidal configurations of the molecule The corresponding double minimum vibrational potential leads to a splitting of the vibrational levels with two components for 4 , eg, O', 0" and lS, 1" etc; the energy differences between the first two term pairs are 08 cm-' and 358 cm I , respectively The superscript reflects the symmetry of the state In the infrared spectrum, the two bands discussed can be assigned to transitions between components of opposite parity, eg, 1" + OA and 1" +-0" Analysis of the spin functions indicates that, if K = 0, for symmetry reasons of the total wave function only either the.

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